Insertion of Chalcogens and Bis(tert-butylisonitrile)palladium(0) into a Strained Ruthenium Half-sandwich Complex

نویسندگان

  • Holger Braunschweig
  • Alexander Damme
  • Jan Mies
  • Marius Schäfer
چکیده

The previously synthesized strained distannadiyl-ansa half-sandwich complex [{κ-SntBu2SntBu2-(η-C5H5)}Ru(CO)2] was investigated with respect to its reactivity toward group 16 elements and bis(tert-butylisonitrile)palladium(0). All products were analyzed by multinuclear NMR spectroscopy, IR spectroscopy and elemental analysis. [{κ-SntBu2SSntBu2-(η-C5H5)}Ru(CO)2] was furthermore characterized by X-ray diffraction.

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تاریخ انتشار 2012